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Bis((R)-2,2'-Bis(Diphenylphosphino)-1,1' -Binaphthyl)Rhodium(I) Perchlorate, 96 CAS NO 95156-21-1


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CAS No.:95156-21-1

Grade:Pharmacy Grade

Content:99.9%

Brand:Customizable

Packaging:Customizable

Description

Bis((R)-2,2'-Bis(Diphenylphosphino)-1,1' -Binaphthyl)Rhodium(I) Perchlorate, 96 is a high-purity, chiral organometallic complex widely recognized as a highly effective asymmetric hydrogenation catalyst. This compound is valued for its exceptional enantioselectivity and catalytic activity in the synthesis of chiral intermediates. It is primarily utilized by research institutions and industrial manufacturers in the pharmaceutical, agrochemical, and fine chemical sectors for producing optically active compounds.

Application

  • Asymmetric Hydrogenation Catalyst: For the enantioselective reduction of prochiral olefins, ketones, and imines in pharmaceutical intermediate synthesis.
  • Pharmaceutical Manufacturing: Key catalyst in the production of chiral active pharmaceutical ingredients (APIs), such as certain antibiotics, anti-inflammatory drugs, and cardiovascular agents.
  • Agrochemical Synthesis: Used in the preparation of enantiomerically pure herbicides, fungicides, and plant growth regulators.
  • Fine Chemical Production: Enables the synthesis of specialty chemicals, flavors, and fragrances requiring high optical purity.
  • Academic & Industrial Research: A benchmark catalyst for developing new asymmetric synthetic methodologies and studying catalytic mechanisms.
  • Material Science: Potential applications in the development of chiral polymers and advanced functional materials.

Basic Information

Product Name Bis((R)-2,2'-Bis(Diphenylphosphino)-1,1' -Binaphthyl)Rhodium(I) Perchlorate, 96
CAS No. 95156-21-1
Molecular Formula C₁₀₄H₇₂ClO₄P₄Rh
Molecular Weight 1625.84 g/mol
Synonyms (R)-BINAP-Rhodium(I) Perchlorate; [Rh((R)-BINAP)₂]ClO₄; Bis[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rhodium(I) perchlorate; (R)-BINAP-Rh⁺ complex; Rh((R)-BINAP)₂ClO₄; Rhodium(I) (R)-BINAP perchlorate; Asymmetric hydrogenation catalyst Rh-(R)-BINAP; (R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl rhodium(I) perchlorate dimer
EINECS Contact for details

Quality Control

Our Bis((R)-2,2'-Bis(Diphenylphosphino)-1,1' -Binaphthyl)Rhodium(I) Perchlorate, 96 is manufactured under strict quality protocols to ensure batch-to-batch consistency and high catalytic performance. Each lot undergoes rigorous analytical testing, including HPLC for purity and NMR for structural confirmation. Certificates of Analysis (COA) detailing all specifications are available upon request.

Storage

Preserve in a tightly closed container, protected from light. Store in a cool, dry place at a controlled room temperature (15-25°C). This compound is a strong oxidizer and light-sensitive; it should be kept separate from reducing agents and combustible materials. For long-term stability, consider storage under an inert atmosphere.

Specification

Item Specification
Appearance Orange to red-brown crystalline powder
Identification (IR) Conforms to structure
Purity (HPLC) ≥ 96.0%
Specific Rotation Contact for details
Solubility Soluble in dichloromethane, chloroform; slightly soluble in toluene
Heavy Metals < 20 ppm
Residual Solvents (GC) Meets ICH guidelines

Note: Specifications can be tailored. Please contact us for the detailed technical data sheet of a specific grade.

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