Description

Bis(Cyclooctadiene)Rhodium(Ⅰ)(Tetrakis-[3,5-Bis(Trifluormethyl)Phenyl]Borate) is a highly specialized organorhodium(I) complex, valued for its exceptional catalytic activity in demanding chemical transformations. This compound is critical for enabling precise and efficient synthetic routes in advanced chemical research and development. It is primarily sought after by R&D chemists and process engineers in the pharmaceutical, fine chemical, and advanced materials sectors for applications requiring high-performance, air-sensitive catalysts.

Application

• Catalyst for C-H Activation: A key precursor for developing catalysts used in selective C-H bond functionalization reactions, crucial for streamlining complex molecule synthesis.
• Asymmetric Hydrogenation: Employed in the synthesis of chiral ligands and complexes for the enantioselective hydrogenation of prochiral substrates in pharmaceutical intermediate production.
• Cross-Coupling Reactions: Serves as a catalyst or catalyst precursor in various carbon-carbon and carbon-heteroatom bond-forming reactions under mild conditions.
• Polymerization Catalyst: Used in research for the development of novel catalytic systems for the polymerization of specific monomers to create advanced polymeric materials.
• Academic & Industrial R&D: A fundamental reagent for methodological development in organometallic chemistry and catalysis research.
• Fine Chemical Synthesis: Facilitates the synthesis of high-value, structurally complex fine chemicals and active pharmaceutical ingredients (APIs).

Basic Information

Product Name	Bis(Cyclooctadiene)Rhodium(Ⅰ)(Tetrakis-[3,5-Bis(Trifluormethyl)Phenyl]Borate)
CAS No.	404573-66-6
Molecular Formula	C48H32BF24Rh
Molecular Weight	1194.36 g/mol
Synonyms	Rh(COD)2BARF; [Rh(COD)2][B(3,5-(CF3)2C6H3)4]; Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; Rh(COD)2BArF4; Rhodium(1+) bis(1,5-cyclooctadiene)-, (OC-6-11)-, tetrakis[3,5-bis(trifluoromethyl)phenyl]borate(1-); Rh(COD)2B(3,5-(CF3)2C6H3)4; Bis(cyclooctadiene)rhodium(I) tetrakis(pentafluorophenyl)borate analog
EINECS	Contact for details

Quality Control

Every batch of our Bis(Cyclooctadiene)Rhodium(Ⅰ)(Tetrakis-[3,5-Bis(Trifluormethyl)Phenyl]Borate) is synthesized and handled under strict inert atmosphere conditions to ensure integrity. We employ advanced analytical techniques including NMR, HPLC, and elemental analysis to verify identity, purity, and consistency. A comprehensive Certificate of Analysis (COA) detailing all specifications is provided with each shipment to support your quality assurance protocols.

Storage

Preserve in a tightly closed container, protected from light. Store under an inert atmosphere (argon or nitrogen) at 2-8°C to maintain stability and prevent decomposition. The product is easily oxidized and must be handled in a controlled, moisture-free environment.

Specification

Item	Specification
Appearance	Orange to red crystalline solid
Identification (NMR)	Conforms to structure
Purity (HPLC)	≥ 95%
Rhodium Content	8.0 - 9.0 %
Solubility	Soluble in common organic solvents (DCM, THF, Toluene)

Note: Specifications can be tailored. Please contact us for the detailed technical data sheet of a specific grade.