Description

Chloro[(1,2,3,4,5,6-Eta)-2,2'',4,4'',6,6''-Hexamethyl[1,1':3',1''-Terphenyl]-2'-Thiolato-Kappas][Tris(4-Fluorophenyl)Phosphine-Kappap]Ruthenium(Ii) is a sophisticated organometallic complex featuring a unique hexamethylterphenyl-thiolato ligand and a tris(4-fluorophenyl)phosphine co-ligand. This compound matters as a highly specialized catalyst precursor, offering precise steric and electronic tuning for challenging cross-coupling and hydrogenation reactions in advanced chemical synthesis. It is essential for R&D chemists and process development scientists in the pharmaceutical, agrochemical, and specialty materials industries seeking to develop novel synthetic pathways.

Application

• Catalyst Precursor for C-H Activation: Serves as a key starting material for developing ruthenium-based catalysts used in selective C-H bond functionalization, a critical step in streamlining complex molecule synthesis.
• Advanced Cross-Coupling Reactions: Employed in research for demanding cross-coupling reactions (e.g., Suzuki-Miyaura, Heck) where traditional palladium catalysts are ineffective or require harsher conditions.
• Asymmetric Hydrogenation: Investigated for use in the enantioselective hydrogenation of prochiral substrates to produce single-isomer intermediates for active pharmaceutical ingredients (APIs).
• Polymerization Catalyst Research: Utilized in the development of novel catalytic systems for olefin metathesis or ring-opening polymerization to create polymers with specific architectures.
• Material Science & OLED Development: Acts as a potential source of ruthenium for depositing thin films or as a molecular dopant in the research of next-generation organic light-emitting diodes (OLEDs) and other electronic materials.
• Academic & Industrial R&D: A valuable tool for mechanistic studies and exploring new catalytic cycles in both university laboratories and corporate R&D centers focused on organometallic chemistry.

Basic Information

Item	Details
Product Name	Chloro[(1,2,3,4,5,6-Eta)-2,2'',4,4'',6,6''-Hexamethyl[1,1':3',1''-Terphenyl]-2'-Thiolato-Kappas][Tris(4-Fluorophenyl)Phosphine-Kappap]Ruthenium(Ii)
CAS No.	1420299-84-8
Molecular Formula	C46H40ClF3PRuS
Molecular Weight	848.35 g/mol
Synonyms	Ru(hmtt)(P(4-F-C6H4)3)Cl; Chloro(hexamethylterphenyl-2-thiolato)tris(4-fluorophenyl)phosphineruthenium(II); Ruthenium complex with HMTT and TFP ligands; [RuCl(SC6H2-2,4,6-Me3-3-C6H3-2',4',6'-Me3)(P(4-FC6H4)3)]; (Hexamethylterphenylthiolato)chlorotris(4-fluorophenyl)phosphineruthenium; CAS 1420299-84-8
EINECS	Contact for details

Quality Control

Every batch of our Chloro[(1,2,3,4,5,6-Eta)-2,2'',4,4'',6,6''-Hexamethyl[1,1':3',1''-Terphenyl]-2'-Thiolato-Kappas][Tris(4-Fluorophenyl)Phosphine-Kappap]Ruthenium(Ii) is synthesized and handled under stringent inert atmosphere conditions to preserve its integrity. The product undergoes comprehensive analytical characterization, including NMR spectroscopy and elemental analysis (CHNS), to confirm identity and purity. A detailed Certificate of Analysis (COA) documenting all test results is provided with each shipment to ensure full traceability and compliance with your research or quality protocols.

Storage

Preserve in a tightly closed container, protected from light. Store under an inert atmosphere (argon or nitrogen) at 2-8°C to minimize oxidation and thermal degradation. The container should be kept in a cool, dry, and well-ventilated place, away from incompatible materials.

Specification

Item	Specification
Appearance	Dark colored solid
Identification (NMR)	Conforms to structure
Purity (HPLC)	≥ 95%
Elemental Analysis (CHNS)	Within ± 0.4% of theoretical

Note: Specifications can be tailored. Please contact us for the detailed technical data sheet of a specific grade.