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[(R)-(+)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthyl]Palladium(Ii) Chloride CAS NO 115826-95-4


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CAS No.:115826-95-4

Grade:Pharmacy Grade

Content:99.9%

Brand:Customizable

Packaging:Customizable

Description

[(R)-(+)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthyl]Palladium(II) Chloride is a highly specialized, chiral palladium complex that serves as a premier catalyst for asymmetric synthesis. Its value lies in enabling highly enantioselective carbon-carbon and carbon-heteroatom bond-forming reactions, which are critical for producing single-isomer pharmaceutical intermediates and fine chemicals. This product is essential for R&D chemists and process development scientists in the pharmaceutical, agrochemical, and advanced materials sectors who require precise stereochemical control.

Application

  • Asymmetric Cross-Coupling Reactions: A key catalyst for enantioselective Suzuki-Miyaura, Negishi, and Buchwald-Hartwig amination reactions.
  • Pharmaceutical Intermediate Synthesis: Critical for the production of chiral active pharmaceutical ingredients (APIs) and key synthons.
  • Agrochemical Research: Used in the development of enantiomerically pure herbicides, fungicides, and plant growth regulators.
  • Academic & Industrial R&D: A valuable tool for methodology development in organic synthesis and catalysis studies.
  • Fine Chemical Manufacturing: Enables the scalable production of high-value, chiral specialty chemicals and ligands.
  • Material Science: Potential applications in creating chiral polymers or frameworks with specific optical properties.

Basic Information

Product Name [(R)-(+)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthyl]Palladium(II) Chloride
CAS No. 115826-95-4
Molecular Formula C44H32Cl2P2Pd
Molecular Weight 804.93 g/mol
Synonyms (R)-(+)-BINAP-PdCl2; (R)-BINAP Palladium(II) Chloride; (R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl Palladium Dichloride; Pd[(R)-BINAP]Cl2; (R)-BINAP PdCl2 Complex; Palladium(II) (R)-BINAP Chloride; (R)-(-)-1,1'-Binaphthalene-2,2'-diyl)bis(diphenylphosphine) Palladium(II) Chloride
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Quality Control

Every batch of our [(R)-(+)-BINAP-PdCl2] is synthesized and purified under stringent conditions to ensure exceptional catalytic activity and enantiomeric purity. We employ advanced analytical techniques, including NMR, HPLC, and elemental analysis, to verify identity, purity, and the absence of deleterious impurities. A comprehensive Certificate of Analysis (COA) detailing all specifications is provided with each shipment to support your quality assurance protocols.

Storage

Preserve in a tightly closed container, protected from light. Store in a cool, dry place at a controlled room temperature (15-25°C). This material is light-sensitive and should be handled under an inert atmosphere when possible to maintain optimal catalytic performance. Keep away from incompatible materials.

Specification

Item Specification
Appearance Orange to red-brown powder or crystals
Identification (IR) Conforms to structure
Purity (HPLC) ≥ 98.0%
Chiral Purity (HPLC) ≥ 99.0% ee
Pd Content 13.0 - 13.5%
Solubility Soluble in dichloromethane, chloroform; slightly soluble in toluene

Note: Specifications can be tailored. Please contact us for the detailed technical data sheet of a specific grade.

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