Description

trans-Chloro(1-Naphthyl)Bis(Triphenylphosphine)-Nickel is a highly specialized organometallic complex, valued for its role as a versatile catalyst in advanced organic synthesis. This compound is essential for facilitating challenging cross-coupling and carbon-heteroatom bond formation reactions with high selectivity. It is primarily needed by R&D chemists and process engineers in the pharmaceutical, agrochemical, and advanced materials sectors for developing novel compounds and optimizing synthetic routes.

Application

• Catalyst for Cross-Coupling Reactions: A key component in Negishi, Kumada, and related nickel-catalyzed cross-coupling reactions for forming C-C bonds.
• Pharmaceutical Intermediate Synthesis: Used in the research and development of active pharmaceutical ingredients (APIs), particularly for constructing complex biaryl and heteroaryl structures.
• Agrochemical Product Development: Employed in the synthesis of novel herbicides, fungicides, and insecticides requiring specific aryl-nickel intermediates.
• Materials Science Research: Facilitates the synthesis of conjugated polymers and organic electronic materials through controlled polymerization or functionalization.
• Methodology Development in Academia: A valuable reagent for developing new catalytic methodologies and studying reaction mechanisms in university and institutional labs.
• Fine Chemical Synthesis: Applied in the production of specialty chemicals, flavors, and fragrances where precise metal-mediated transformations are required.

Basic Information

Item	Details
Product Name	trans-Chloro(1-Naphthyl)Bis(Triphenylphosphine)-Nickel
CAS No.	54806-25-6
Molecular Formula	C49H40ClNiP2
Molecular Weight	770.00 g/mol
Synonyms	trans-Chloro(1-naphthyl)bis(triphenylphosphine)nickel(II); (1-Naphthyl)nickel(II) chloride bis(triphenylphosphine); Nickel, chloro(1-naphthalenyl-C)bis(triphenylphosphine)-, (SP-4-2)-; Chloro(1-naphthyl)bis(triphenylphosphine)nickel; trans-(1-Naphthyl)NiCl(PPh3)2; NiCl(1-Naph)(PPh3)2; Organonickel catalyst 54806-25-6
EINECS	Contact for details

Quality Control

Our trans-Chloro(1-Naphthyl)Bis(Triphenylphosphine)-Nickel is produced under controlled conditions to ensure batch-to-batch consistency and high catalytic activity. Each lot undergoes rigorous quality testing, including spectroscopic identification and purity assessment, to ensure compliance with stringent research-grade standards. A comprehensive Certificate of Analysis (COA) detailing assay, identity, and impurity profiles is available upon request to support your quality and regulatory documentation.

Storage

Preserve in a tightly closed container, protected from light. Store under an inert atmosphere (argon or nitrogen) at 2-8°C to minimize oxidation and decomposition. Keep the container in a cool, dry, well-ventilated place, away from incompatible materials.

Specification

Item	Specification
Appearance	Green to brown crystalline solid
Identification (IR)	Conforms to structure
Assay (Ni content)	≥ 95.0%
Purity (HPLC)	≥ 97.0%
Solubility	Soluble in common organic solvents (THF, Toluene, DCM)

Note: Specifications can be tailored. Please contact us for the detailed technical data sheet of a specific grade.