Description

Iridium(1+), [4,4′-Bis(Trifluoromethyl)-2,2′-Bipyridine-κn1,κn1′]Bis[3,5-Difluoro-2-(5-Fluoro-2-Pyridinyl-κn)Phenyl-κc]-, Hexafluorophosphate(1-) (1:1) is a highly specialized organometallic complex featuring a cationic iridium(III) center coordinated by a cyclometalated ligand system. This compound is valued for its exceptional photophysical properties, making it a critical material for advanced optoelectronic research and development. It is primarily sought by R&D teams and manufacturers in the fields of organic light-emitting diodes (OLEDs), photoredox catalysis, and luminescent sensors.

Application

• Phosphorescent Emitter in OLEDs: Serves as a key dopant material in the emissive layer of high-efficiency, next-generation OLED displays and lighting due to its potential for high color purity and quantum yield.
• Photoredox Catalyst: Enables novel organic synthesis pathways under mild, visible-light irradiation for pharmaceutical and fine chemical manufacturing.
• Luminescent Probe/Sensor: Used in the development of chemical sensors and bio-imaging agents that rely on luminescence quenching or enhancement.
• Material Science Research: A fundamental building block for studying charge transfer, excited-state dynamics, and the development of new photoactive materials.
• Light-Harvesting Complexes: Investigated for use in dye-sensitized solar cells (DSSCs) and artificial photosynthesis systems.

Basic Information

Product Name	Iridium(1+), [4,4′-Bis(Trifluoromethyl)-2,2′-Bipyridine-κn1,κn1′]Bis[3,5-Difluoro-2-(5-Fluoro-2-Pyridinyl-κn)Phenyl-κc]-, Hexafluorophosphate(1-) (1:1)
CAS No.	2229858-25-5
Molecular Formula	C₃₈H₁₈F₁₆IrN₄P
Molecular Weight	1081.66 g/mol
Synonyms	Iridium(III) bis(3,5-difluoro-2-(5-fluoropyridin-2-yl)phenyl)(4,4'-bis(trifluoromethyl)-2,2'-bipyridine) hexafluorophosphate; [Ir(dFppy)₂(dtbbpy)]PF₆ (with specific fluorinated ligands); Iridium complex with fluorinated cyclometalating and ancillary ligands; Photoredox catalyst Ir-F; Hexafluorophosphate salt of cationic iridium complex; OLED phosphor emitter (fluorinated series); (dfppy)₂Ir(dtbbpy)PF₆
EINECS	Contact for details

Quality Control

Every batch of our high-purity iridium complex is synthesized and purified under controlled conditions to ensure exceptional consistency for research and development. We employ advanced analytical techniques including HPLC, NMR, and elemental analysis to verify chemical identity and purity. A comprehensive Certificate of Analysis (COA) detailing batch-specific results is provided with each shipment to support your quality assurance protocols.

Storage

Preserve in a tightly closed container, protected from light. Store in a cool, dry place at room temperature (15-25°C). This material is hygroscopic (moisture-sensitive) and should be handled under an inert atmosphere (e.g., nitrogen or argon) when possible to prevent degradation. Keep the container tightly sealed in a desiccator for long-term storage.

Specification

Item	Specification
Appearance	Orange to red crystalline powder
Identification (IR)	Conforms to structure
Identification (NMR)	Conforms to structure
Purity (HPLC)	≥ 98.0% (Area %)
Residual Solvents (GC)	Meets ICH guidelines
Elemental Analysis	Within theoretical ± 0.4%
Water Content (KF)	≤ 0.5% w/w

Note: Specifications can be tailored. Please contact us for the detailed technical data sheet of a specific grade.