Description

Aqua(6,6'-Dihydroxy-2,2'-Bipyridine)(Pentamethylcyclopentadienyl)Iridium(III)Bis(Triflate) is a highly specialized organometallic iridium complex designed for advanced catalytic and photophysical applications. This compound is valued for its unique electronic properties derived from the pentamethylcyclopentadienyl and dihydroxybipyridine ligands, which make it a powerful and selective catalyst precursor. It is primarily sought by researchers and process chemists in the fields of homogeneous catalysis, organic light-emitting diode (OLED) materials development, and photoredox catalysis.

Application

• Homogeneous Catalysis: Acts as a high-performance catalyst precursor for C-H activation, hydrogenation, and other bond-forming reactions under mild conditions.
• Photoredox Catalysis: Serves as a key component in visible-light-mediated organic transformations due to its favorable excited-state redox properties.
• OLED Emitter Development: Used in the research and synthesis of phosphorescent dopants and emitters for next-generation display and lighting technologies.
• Water Oxidation Catalysis (WOC): Investigated as a molecular catalyst for artificial photosynthesis and solar fuel generation systems.
• Luminescent Sensor Probes: Employed in the design of sensitive and selective chemical sensors based on luminescence quenching or enhancement.
• Academic & Industrial R&D: A critical reagent for exploring new reaction methodologies and developing novel organometallic frameworks.

Basic Information

Product Name	Aqua(6,6'-Dihydroxy-2,2'-Bipyridine)(Pentamethylcyclopentadienyl)Iridium(III)Bis(Triflate)
CAS No.	1360870-69-4
Molecular Formula	C₂₇H₂₇F₆IrN₂O₉S₂
Molecular Weight	915.90 g/mol
Synonyms	Aqua(6,6'-dihydroxy-2,2'-bipyridine)(η⁵-pentamethylcyclopentadienyl)iridium(III) bis(trifluoromethanesulfonate); Cp*Ir(dhbpy)OH₂(OTf)₂; (Pentamethylcyclopentadienyl)(6,6'-dihydroxy-2,2'-bipyridine)aquairidium(III) bis(triflate); Iridium(III) Cp* complex with 6,6'-dihydroxy-2,2'-bipyridine; Aqua(pentamethylcyclopentadienyl)(6,6'-dihydroxy-2,2'-bipyridine)iridium bis(trifluoromethanesulfonate); [Ir(Cp*)(dhbpy)(OH₂)](OTf)₂
EINECS	Contact for details

Quality Control

Every batch of our high-value organometallic complexes is synthesized and handled under strict inert atmosphere conditions to ensure integrity. We employ advanced analytical techniques including NMR (¹H, ¹³C, ¹⁹F), HPLC, and elemental analysis (CHNS) for comprehensive characterization and purity verification. A detailed Certificate of Analysis (COA) is provided with each shipment, confirming identity, purity, and conformity to the agreed specifications.

Storage

Preserve in a tightly closed container, protected from light. Store under an inert atmosphere (argon or nitrogen) at 2-8°C in a dedicated freezer. This compound is hygroscopic (moisture-sensitive) and must be handled in a dry, controlled environment to prevent decomposition.

Specification

Item	Specification
Appearance	Orange to red crystalline or microcrystalline solid
Identification (IR)	Conforms to structure
Identification (NMR)	Conforms to structure
Purity (HPLC)	≥ 95% (Area %)
Water Content (KF)	≤ 2.0 %
Solvent Residue (GC)	Meets ICH guidelines

Note: Specifications can be tailored. Please contact us for the detailed technical data sheet of a specific grade.